Ketone synthesis by intramolecular acylation of organorhodium(I) with ester

被引：126

作者：

Miura, T ^{[1
]}

Sasaki, T ^{[1
]}

Nakazawa, H ^{[1
]}

Murakami, M ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 05期

关键词：

D O I：

10.1021/ja043123i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle. Copyright © 2005 American Chemical Society.

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页码：1390 / 1391

页数：2

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