6,6′-Bisperfluoroalkylated BINOLs promoted asymmetric allylation of aldehydes

被引：16

作者：

Yin, YY ^{[1
]}

Zhao, G ^{[1
]}

Qian, ZS ^{[1
]}

Yin, WX ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 120卷 / 02期

关键词：

Rf-BINOL; fluorous biphase; asymmetric allylation;

D O I：

10.1016/S0022-1139(02)00319-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

6,6'-Bis(1H, 1H, 2H, 2H-perfluorooctyl)-1, 1'-bi-2-naphthol (Rf(6)-BINOL) and 6,6'-bis(1H, 1H, 2H, 2H-perfluorodecyl)-1,1'-bi-2-naphthol (Rf(8)-BINOL) were used in allylation of aldehydes in fluorous biphase system. Good enantioselectivity was obtained and the ligands could be recovered by continuos liquid-liquid extraction. (C) 2002 Elsevier Science B.V. All rights reserved.

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收藏

页码：117 / 120

页数：4

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