Gold(I)-catalyzed enantioselective intramolecular hydroamination of allenes

被引：389

作者：

LaLonde, Rebecca L. ^{[1
]}

Sherry, Benjamin D. ^{[1
]}

Kang, Eun Joo ^{[1
]}

Toste, F. Dean ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 09期

关键词：

D O I：

10.1021/ja068819l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The asymmetric intramolecular hydroamination of allenes catalyzed by phosphinegold(I)-bis-p-nitrobenzoate complexes is described. This reaction is applicable to the enantioselective formation of vinyl pyrrolidines and piperidines in 70-99% ee.

引用

页码：2452 / +

页数：3

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