Large magnetic moment observed in Co-doped ZnO nanocluster-assembled thin films at room temperature

被引:53
作者
Zhao, Z. W. [1 ]
Tay, B. K.
Chen, J. S.
Hu, J. F.
Lim, B. C.
Li, G. P.
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 637798, Singapore
[2] Data Storage Inst, Singapore 117608, Singapore
[3] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 119260, Singapore
[4] Lanzhou Univ, Sch Nucl Sci & Technol, Lanzhou 730000, Peoples R China
关键词
D O I
10.1063/1.2721140
中图分类号
O59 [应用物理学];
学科分类号
摘要
Co-doped ZnO nanocluster-assembled films were deposited by nanocluster-beam deposition. Zn0.986Co0.014O nanoclusters remained wurtzite in structure with size of 5 nm. Compared with bulk ZnO, a blueshift of 0.28 eV was observed in the absorption edge of the film. Two photo-luminescence bands at 378 and 510 nm were detected. Room-temperature ferromagnetism was observed in doped ZnO nanocluster-assembled film. Moreover, it exhibited a large saturated magnetization of 1.4 mu(B)/Co and increased to 3.65 mu(B)/Co after the film was annealed. The possible mechanisms on the observed ferromagnetism and enhanced magnetic moment were discussed. (c) 2007 American Institute of Physics.
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页数:3
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