Morphological control of room-temperature ionic liquid templated mesoporous silica nanoparticles for controlled release of antibacterial agents

被引:387
作者
Trewyn, BG [1 ]
Whitman, CM [1 ]
Lin, VSY [1 ]
机构
[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
关键词
D O I
10.1021/nl048774r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of room-temperature ionic liquid (RTIL) containing mesoporous silica nanoparticle (MSN) materials with various particle morphologies, including spheres, ellipsoids, rods, and tubes, were synthesized. By changing the RTIL template, the pore morphology was tuned from the MCM-41 type of hexagonal mesopores to rotational moire type of helical channels, and to wormhole-like porous structures. These materials were used as controlled release delivery nanodevices to release antibacterial ionic liquids against Escherichia coli K12.
引用
收藏
页码:2139 / 2143
页数:5
相关论文
共 27 条
[21]   Engineering uniform active sites in inorganic solid catalysts [J].
Thomas, JM .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) :77-85
[22]   Synthesis and characterisation of ibuprofen-anchored MCM-41 silica and silica gel [J].
Tourné-Péteilh, C ;
Brunel, D ;
Bégu, S ;
Chiche, B ;
Fajula, F ;
Lerner, DA ;
Devoisselle, JM .
NEW JOURNAL OF CHEMISTRY, 2003, 27 (10) :1415-1418
[23]   A new property of MCM-41:: Drug delivery system [J].
Vallet-Regi, M ;
Rámila, A ;
del Real, RP ;
Pérez-Pariente, J .
CHEMISTRY OF MATERIALS, 2001, 13 (02) :308-311
[24]   Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores [J].
Zhao, DY ;
Feng, JL ;
Huo, QS ;
Melosh, N ;
Fredrickson, GH ;
Chmelka, BF ;
Stucky, GD .
SCIENCE, 1998, 279 (5350) :548-552
[25]   A series of highly ordered, super-microporus, lamellar silicas prepared by nanocasting with ionic liquids [J].
Zhou, Y ;
Antonietti, M .
CHEMISTRY OF MATERIALS, 2004, 16 (03) :544-550
[26]   Room-temperature ionic liquids as template to monolithic mesoporous silica with wormlike pores via a sol-gel nanocasting technique [J].
Zhou, Y ;
Schattka, JH ;
Antonietti, M .
NANO LETTERS, 2004, 4 (03) :477-481
[27]   Preparation of highly ordered monolithic super-microporous lamellar silica with a room-temperature ionic liquid as template via the nanocasting technique [J].
Zhou, Y ;
Antonietti, M .
ADVANCED MATERIALS, 2003, 15 (17) :1452-1455