Labeling of organic biomolecules with ethynylferrocene

被引：45

作者：

Coutouli-Argyropoulou, E ^{[1
]}

Tsitabani, M

Petrantonakis, G

Terzis, A

Raptopoulou, C

机构：

[1] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece

[2] NCSR Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Attiki, Greece

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 08期

关键词：

D O I：

10.1039/b300191a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Sonogashira coupling reaction of ethynylferrocene with adenine, uracil, tyrosine and steroid derivatives was studied; with the exception of tyrosine it was proved to be a good route for the attachment of ferrocene to these representative biomolecules. In addition the transformation of alkynyl uracil to furanopyrimidone derivatives was investigated and the formation of the furanopyrimidone ring was confirmed by an X-ray crystallographic analysis carried out on product 16.

引用

页码：1382 / 1388

页数：7

共 65 条

[1] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
Amatore, C
Jutand, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
[2] Synthesis of the first ferrocene-labeled dideoxynucleotide and its use for 3′-redox end-labeling of 5′-modified single-stranded oligonucleotides
Anne, A
Blanc, B
Moiroux, J
[J]. BIOCONJUGATE CHEMISTRY, 2001, 12 (03) : 396 - 405
[3] Novel monolabeled redox biomaterials: Amino-ended poly(ethylene oxide) ferrocenes and their biotin-conjugates
Anne, A
[J]. TETRAHEDRON LETTERS, 1998, 39 (07) : 561 - 564
[4] Synthesis of unsymmetrical 1,1′-disubstituted ferrocenes.: Formation of ferrocenophanes via intramolecular cycloaddition
Argyropoulos, N
Coutouli-Argyropoulou, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 654 (1-2) : 117 - 122
[5] Recent developments in faradaic bioelectrochemistry
Armstrong, FA
Wilson, GS
[J]. ELECTROCHIMICA ACTA, 2000, 45 (15-16) : 2623 - 2645
[6] Electrochemical sensors
Bakker, E
Telting-Diaz, M
[J]. ANALYTICAL CHEMISTRY, 2002, 74 (12) : 2781 - 2800
[7] On-column derivatization of oligodeoxynucleotides with ferrocene
Beilstein, AE
Grinstaff, MW
[J]. CHEMICAL COMMUNICATIONS, 2000, (06) : 509 - 510
[8] Synthesis and characterization of ferrocene-labeled oligodeoxynucleotides
Beilstein, AE
Grinstaff, MW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 398 - 406
[9] MOLECULAR FLUORESCENT SIGNALING WITH FLUOR SPACER RECEPTOR SYSTEMS - APPROACHES TO SENSING AND SWITCHING DEVICES VIA SUPRAMOLECULAR PHOTOPHYSICS
BISSELL, RA
DE SILVA, AP
GUNARATNE, HQN
LYNCH, PLM
MAGUIRE, GEM
SANDANAYAKE, KRAS
[J]. CHEMICAL SOCIETY REVIEWS, 1992, 21 (03) : 187 - 195
[10] Capillary gel electrophoresis with sinusoidal voltammetric detection: A strategy to allow four-"color" DNA sequencing
Brazill, SA
Kim, PH
Kuhr, WG
[J]. ANALYTICAL CHEMISTRY, 2001, 73 (20) : 4882 - 4890

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