Recent trends in carbon negative electrode materials

被引：20

作者：

Kasuh, T ^{[1
]}

Mabuchi, A ^{[1
]}

Tokumitsu, K ^{[1
]}

Fujimoto, H ^{[1
]}

机构：

[1] Osaka Gas Co Ltd, Ctr Res & Dev, Konohana Ku, Osaka 554, Japan

来源：

JOURNAL OF POWER SOURCES | 1997年 / 68卷 / 01期

关键词：

carbon; electrode materials; negative electrodes; rechargeable lithium batteries;

D O I：

10.1016/S0378-7753(97)02582-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of graphite-type materials as the negative electrodes for rechargeable lithium batteries is increasing. For graphite-type materials, we proposed the intercalation mechanism taking into account the influence of crystallite size and stacking of the graphitic layers. We found graphite-type materials with a reversible capacity of 430 mAh g(-1) over a theoretical limit capacity of 372 mAh g(-1). This higher capacity is due to cavities existing in carbon that are capable of storing lithium ions. (C) 1997 Elsevier Science S.A.

引用

页码：99 / 101

页数：3

共 10 条

[1] EFFECT OF CRYSTALLITE SIZE ON THE CHEMICAL-COMPOSITIONS OF THE STAGE-1 ALKALI METAL-GRAPHITE INTERCALATION COMPOUNDS [J].

FUJIMOTO, H ;

MABUCHI, A ;

TOKUMITSU, K ;

KASUH, T ;

AKUZAWA, N .

CARBON, 1994, 32 (02) :193-198

[2] NEW STRUCTURAL PARAMETERS FOR CARBON - COMPREHENSIVE CRYSTALLIZATION INDEX AND CAVITY INDEX [J].

FUJIMOTO, H ;

TOKUMITSU, K ;

MABUCHI, A ;

KASUH, T ;

SHIRAISHI, M .

CARBON, 1994, 32 (07) :1249-1252

[3]

FUJIMOTO H, 1995, P 22 ANN M CARB SOC, pA309

[4]

FUJIMOTO H, UNPUB CARBON

[5] CHARGE-DISCHARGE MECHANISM OF GRAPHITIZED MESOCARBON MICROBEADS [J].

MABUCHI, A ;

FUJIMOTO, H ;

TOKUMITSU, K ;

KASUH, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (09) :3049-3051

[6] CHARGE-DISCHARGE CHARACTERISTICS OF THE MESOCARBON MICROBEADS HEAT-TREATED AT DIFFERENT TEMPERATURES [J].

MABUCHI, A ;

TOKUMITSU, K ;

FUJIMOTO, H ;

KASUH, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (04) :1041-1046

[7] A MECHANISM OF LITHIUM STORAGE IN DISORDERED CARBONS [J].

SATO, K ;

NOGUCHI, M ;

DEMACHI, A ;

OKI, N ;

ENDO, M .

SCIENCE, 1994, 264 (5158) :556-558

[8] THE INFLUENCE OF THE GRAPHITIC STRUCTURE ON THE ELECTROCHEMICAL CHARACTERISTICS FOR THE ANODE OF SECONDARY LITHIUM BATTERIES [J].

TATSUMI, K ;

IWASHITA, N ;

SAKAEBE, H ;

SHIOYAMA, H ;

HIGUCHI, S ;

MABUCHI, A ;

FUJIMOTO, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (03) :716-720

[9] STRUCTURE AND PROPERTIES OF DEEPLY LI-DOPED POLYACENIC SEMICONDUCTOR-MATERIALS BEYOND C6LI STAGE [J].

YATA, S ;

KINOSHITA, H ;

KOMORI, M ;

ANDO, N ;

KASHIWAMURA, T ;

HARADA, T ;

TANAKA, K ;

YAMABE, T .

SYNTHETIC METALS, 1994, 62 (02) :153-158

[10] LITHIUM INSERTION IN HIGH-CAPACITY CARBONACEOUS MATERIALS [J].

ZHENG, T ;

LIU, YH ;

FULLER, EW ;

TSENG, S ;

VONSACKEN, U ;

DAHN, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2581-2590

← 1 →