Lewis acid mediated P-P bond hydrogenation and hydrosilylation

被引：29

作者：

Geier, Stephen J. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SYNTHETIC APPROACH; PHOSPHINE; REACTIVITY; COMPLEXES; HYDROSILATION; COORDINATION; CATIONS; P-4; ACTIVATION; ACCEPTOR;

D O I：

10.1039/b925126j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of H-2, R3SiH or R2SiH2 with P5Ph5 in the presence of stoichiometric B(C6F5)(3) results in excellent yields of the phosphine-borane adducts (PhPH2)B(C6F5)(3), ((R3Si)PhPH)B(C6F5)(3) and ((R2SiH)PhPH)B(C6F5)(3), respectively.

引用

页码：1026 / 1028

页数：3

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