Conjugated polyelectrolytes as fluorescent sensors

被引:162
作者
Liu, Yan [1 ]
Ogawa, Katsu [1 ]
Schanze, Kirk S. [1 ]
机构
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
关键词
Conjugated polymer; Conjugated polyelectrolyte; Fluorescence; Sensor; Biosensor; Quenching; SOLUBLE POLY(PHENYLENE ETHYNYLENE); HIGHLY SENSITIVE DETECTION; MOLECULAR WIRE APPROACH; ENERGY-TRANSFER; POLYMER FLUORESCENCE; OPTICAL PROBES; DNA DETECTION; CHAIN-LENGTH; AGGREGATION; PHOTOLUMINESCENCE;
D O I
10.1016/j.jphotochemrev.2009.10.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Conjugated polyelectrolytes (CPEs) have become one of the most utilized materials in chemo- and bio-sensory systems. Useful properties of CPEs, such as amplified quenching effects and aggregation behavior, are illustrated in detail in order to provide guidelines for underlying concepts of CPE-based sensors. Well established sensing mechanisms, such as conformational changes and fluorescence resonance energy transfer, are reviewed with representative examples. Target species include small ions, small biomolecules, proteins, enzymatic activities, and DNA. New and unique mechanisms for CPE-based sensing are also described. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:173 / 190
页数:18
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