Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

被引：83

作者：

Delp, Samuel A.

Munro-Leighton, Colleen

Goj, Laurel A.

Ramirez, Magaly A.

Gunnoe, T. Brent

Petersen, Jeffrey L.

Boyle, Paul D.

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

[2] W Virginia Univ, C Eugene Bennett Dept Chem, Morgantown, WV 26506 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 07期

关键词：

D O I：

10.1021/ic070268s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S-H bonds across electron-deficient olefins to regioselectively produce "anti-Markovnikov" products.

引用

收藏

页码：2365 / 2367

页数：3

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