A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores

被引：263

作者：

Feng, Dawei ^{[1
]}

Wang, Kecheng ^{[1
]}

Su, Jie ^{[2
]}

Liu, Tian-Fu ^{[1
]}

Park, Jihye ^{[1
]}

Wei, Zhangwen ^{[1
]}

Bosch, Mathieu ^{[1
]}

Yakovenko, Andrey ^{[3
]}

Zou, Xiaodong ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat & Inorgan & Stru, S-10691 Stockholm, Sweden

[3] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 01期

关键词：

carboxylate ligands; host-guest systems; mesoporous materials; metal-organic frameworks; zirconium; WATER OXIDATION; UIO-66; DIFFRACTION; ADSORPTION; LIGAND; CHEMISTRY; CATALYSTS; EXCHANGE; DEFECTS; ROBUST;

D O I：

10.1002/anie.201409334

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.

引用

收藏

页码：149 / 154

页数：6

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