Cost efficient synthesis of amides from oximes with indium or zinc catalysts

被引：88

作者：

Allen, C. Liana ^{[1
]}

Burel, Celine ^{[1
]}

Williams, Jonathan M. J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

ONE-POT SYNTHESIS; BECKMANN REARRANGEMENT; HIGHLY EFFICIENT; MICROWAVE IRRADIATION; BOND FORMATION; SOLVENT-FREE; ALDEHYDES; NITRILES; CONVERSION; ALDOXIMES;

D O I：

10.1016/j.tetlet.2010.03.048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple indium and zinc salts have been successfully used as catalysts for the rearrangement of oximes into primary amides. The direct synthesis of nitriles or primary amides from aldehydes has also been demonstrated using these inexpensive catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

引用

收藏

页码：2724 / 2726

页数：3

相关论文

共 36 条

[1] Palladium-Catalyzed One-Pot Conversion of Aldehydes to Amides [J].

Ali, Md Ashif ;

Punniyamurthy, Tharmalingam .

ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (2-3) :288-292

[2] An efficient one-pot synthesis of aromatic nitriles from aldehydes using Fe modified K10. [J].

Bajpai, AR ;

Deshpande, AB ;

Samant, SD .

SYNTHETIC COMMUNICATIONS, 2000, 30 (15) :2785-2791

[3] Highly convenient, one-pot synthesis of nitriles from aldehydes using the NH2OH•HCl/NaI/MeCN system [J].

Ballini, R ;

Fiorini, D ;

Palmieri, A .

SYNLETT, 2003, (12) :1841-1843

[4] Organic reactions in water: Transformation of aldehydes to nitriles using NBS under mild conditions [J].

Bandgar, BP ;

Makone, SS .

SYNTHETIC COMMUNICATIONS, 2006, 36 (10) :1347-1352

[5] Catalytic ionic Hydrogenations [J].

Bullock, RM .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (10) :2366-2374

[6] What is a green solvent?: A comprehensive framework for the environmental assessment of solvents [J].

Capello, Christian ;

Fischer, Ulrich ;

Hungerbuehler, Konrad .

GREEN CHEMISTRY, 2007, 9 (09) :927-934

[7] Analysis of the reactions used for the preparation of drug candidate molecules [J].

Carey, John S. ;

Laffan, David ;

Thomson, Colin ;

Williams, Mike T. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (12) :2337-2347

[8] Key green chemistry research areas - a perspective from pharmaceutical manufacturers [J].

Constable, David J. C. ;

Dunn, Peter J. ;

Hayler, John D. ;

Humphrey, Guy R. ;

Leazer, Johnnie L., Jr. ;

Linderman, Russell J. ;

Lorenz, Kurt ;

Manley, Julie ;

Pearlman, Bruce A. ;

Wells, Andrew ;

Zaks, Aleksey ;

Zhang, Tony Y. .

GREEN CHEMISTRY, 2007, 9 (05) :411-420

[9] A cheap metal for a "Noble" task:: Preparative and mechanistic aspects of cycloisomerization and cycloaddition reactions catalyzed by low-valent iron complexes [J].

Fuerstner, Alois ;

Majima, Keisuke ;

Martin, Ruben ;

Krause, Helga ;

Kattnig, Egmont ;

Goddard, Richard ;

Lehmann, Christian W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :1992-2004

[10] A one-pot synthesis of primary amides from aldoximes or aldehydes in water in the presence of a supported rhodium catalyst [J].

Fujiwara, Hiroshi ;

Ogasawara, Yoshiyuki ;

Yamaguchi, Kazuya ;

Mizuno, Noritaka .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (27) :5202-5205

← 1 2 3 4 →