In 6 experiments, the ability of university students to obtain generalizable knowledge about subphonemic distinctive features through learning to read an orthogrphy based on these features was explored. In the reference experiment, learning 4 grapheme-phoneme pairs did not generate feature awareness, as tested by generalization to new instances of the orthography. In a 2nd experiment, this failure was not due to inherent limitations in the testing technique, and a 3rd experiment indicated that a considerable increase in exposure to the orthography and its principles did not help. In the last 3 experiments, instruction in articulatory phoneticss was given prior to subjects'' learning the orthography, but reliable generalization to new instances emerged only when the instruction was based directly on the phonemes used in acquisition. Successful generalization was found to go hand in hand with verbalizable awareness of phonetic structure. A high level of performance was achieved only when the orthogrphy/speech isomorphism was pointed out clearly. Evidently, usable knowledge about an implicitly known property of speech is relatively resistant to instruction via an orthography, and direct in struction in the property is necessary. An analogy is drawn with the acquisition of reading by nonreaders, with the results of the study lending weight to the use of curricula that emphasize phonemic awareness.