CYCLOPROPANATION CATALYZED BY RUCL2(PPH(3))(3) AND OSCL2(PPH(3))(3)

被引：23

作者：

DEMONCEAU, A ^{[1
]}

LEMOINE, CA ^{[1
]}

NOELS, AF ^{[1
]}

CHIZHEVSKY, IT ^{[1
]}

SOROKIN, PV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI, AN NESMEYANOV ORGANOELEMENT CPDS INST, MOSCOW 117813, RUSSIA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 46期

关键词：

D O I：

10.1016/0040-4039(95)01777-F

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

OsCl2(PPh(3))(3) is a cyclopropanation catalyst using ethyl diazoacetate: wi!ha variety of activated alkenes; OsCl2(PPh(3))(3) is however less active than RuCl2(PPh(3))(3) for the decomposition of the diazo reagent and the subsequent cyclopropanation.

引用

页码：8419 / 8422

页数：4

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