STUDIES OF TITANIUM-DIOXIDE FILM GROWTH FROM TITANIUM TETRAISOPROPOXIDE

被引：52

作者：

WU, YM ^{[1
]}

BRADLEY, DC ^{[1
]}

NIX, RM ^{[1
]}

机构：

[1] UNIV LONDON,QUEEN MARY & WESTFIELD COLL,DEPT CHEM,MILE END RD,LONDON E1 4NS,ENGLAND

来源：

APPLIED SURFACE SCIENCE | 1993年 / 64卷 / 01期

关键词：

D O I：

10.1016/0169-4332(93)90018-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface-mediated decomposition of titanium isopropoxide at low pressures has been followed using temperature-programmed reaction spectroscopy and reactive scattering measurements. Film growth is initiated at approximately 450 K, with kinetics controlled by the decomposition of adsorbed intermediates, giving a mixture of acetone, isopropanol and propene as gas-phase by-products. At high temperatures (> 675 K) the principal by-product is propene and adsorption kinetics may become rate-limiting.

引用

页码：21 / 28

页数：8

共 17 条

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