Hydrogen-doped indium oxide/indium tin oxide bilayers for high-efficiency silicon heterojunction solar cells

被引:159
作者
Barraud, L. [1 ]
Holman, Z. C. [1 ]
Badel, N. [1 ]
Reiss, P. [1 ,2 ]
Descoeudres, A. [1 ]
Battaglia, C. [1 ]
De Wolf, S. [1 ]
Ballif, C. [1 ]
机构
[1] EPFL, Inst Microengn IMT, Photovolta & Thin Film Elect Lab, CH-2000 Neuchatel, Switzerland
[2] Helmholtz Zentrum Berlin Mat & Energie, D-12489 Berlin, Germany
关键词
Silicon heterojunction; Solar cell; Transparent conductive oxide; Indium tin oxide; Indium oxide; Contact resistance; TRANSPARENT CONDUCTIVE OXIDE; SILVER NANOPARTICLES; AMORPHOUS-SILICON; WORK FUNCTION; THIN-FILMS; IN2O3;
D O I
10.1016/j.solmat.2013.03.024
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The front transparent conductive oxide layer is a source of significant optical and electrical losses in silicon heterojunction solar cells because of the trade-off between free-carrier absorption and sheet resistance. We demonstrate that hydrogen-doped indium oxide (IO:H), which has an electron mobility of over 100 cm(2)/V s, reduces these losses compared to traditional, low-mobility transparent conductive oxides, but suffers from high contact resistance at the interface of the IO:H layer and the silver front electrode grid. This problem is avoided by inserting a thin indium tin oxide (ITO) layer at the IO:H/silver interface. Such IO:H/ITO bilayers have low contact resistance, sheet resistance, and free-carrier absorption, and outperform IO:H-only or ITO-only layers in solar cells. We report a certified efficiency of 22.1% for a 4-cm(2) screen-printed silicon heterojunction solar cell employing an 10:H/ITO bilayer as the front transparent conductive oxide. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:151 / 156
页数:6
相关论文
共 26 条
[1]   Micromorph thin-film silicon solar cells with transparent high-mobility hydrogenated indium oxide front electrodes [J].
Battaglia, Corsin ;
Erni, Lukas ;
Boccard, Mathieu ;
Barraud, Loris ;
Escarre, Jordi ;
Soederstroem, Karin ;
Bugnon, Gregory ;
Billet, Adrian ;
Ding, Laura ;
Despeisse, Matthieu ;
Haug, Franz-Josef ;
De Wolf, Stefaan ;
Ballif, Christophe .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (11)
[2]   PREPARATION OF CONDUCTING AND TRANSPARENT THIN-FILMS OF TIN-DOPED INDIUM OXIDE BY MAGNETRON SPUTTERING [J].
BUCHANAN, M ;
WEBB, JB ;
WILLIAMS, DF .
APPLIED PHYSICS LETTERS, 1980, 37 (02) :213-215
[3]   Role of front contact work function on amorphous silicon/crystalline silicon heterojunction solar cell performance [J].
Centurioni, E ;
Iencinella, D .
IEEE ELECTRON DEVICE LETTERS, 2003, 24 (03) :177-179
[4]  
De Wolf Stefaan, 2012, Green, V2, P7, DOI 10.1515/green-2011-0018
[5]   Nature of doped a-Si:H/c-Si interface recombination [J].
De Wolf, Stefaan ;
Kondo, Michio .
JOURNAL OF APPLIED PHYSICS, 2009, 105 (10)
[6]   Stretched-exponential a-Si:H/c-Si interface recombination decay [J].
De Wolf, Stefaan ;
Olibet, Sara ;
Ballif, Christophe .
APPLIED PHYSICS LETTERS, 2008, 93 (03)
[7]   Improved amorphous/crystalline silicon interface passivation by hydrogen plasma treatment [J].
Descoeudres, A. ;
Barraud, L. ;
De Wolf, Stefaan ;
Strahm, B. ;
Lachenal, D. ;
Guerin, C. ;
Holman, Z. C. ;
Zicarelli, F. ;
Demaurex, B. ;
Seif, J. ;
Holovsky, J. ;
Ballif, C. .
APPLIED PHYSICS LETTERS, 2011, 99 (12)
[8]   The silane depletion fraction as an indicator for the amorphous/crystalline silicon interface passivation quality [J].
Descoeudres, A. ;
Barraud, L. ;
Bartlome, R. ;
Choong, G. ;
De Wolf, Stefaan ;
Zicarelli, F. ;
Ballif, C. .
APPLIED PHYSICS LETTERS, 2010, 97 (18)
[9]   >21% Efficient Silicon Heterojunction Solar Cells on n- and p-Type Wafers Compared [J].
Descoeudres, Antoine ;
Holman, Zachary C. ;
Barraud, Loris ;
Morel, Sophie ;
De Wolf, Stefaan ;
Ballif, Christophe .
IEEE JOURNAL OF PHOTOVOLTAICS, 2013, 3 (01) :83-89
[10]   SERS Not To Be Taken for Granted in the Presence of Oxygen [J].
Erol, Melek ;
Han, Yun ;
Stanley, Scott K. ;
Stafford, Christopher M. ;
Du, Henry ;
Sukhishvili, Svetlana .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7480-+