Improved amorphous/crystalline silicon interface passivation by hydrogen plasma treatment

被引:243
作者
Descoeudres, A. [1 ]
Barraud, L. [1 ]
De Wolf, Stefaan [1 ]
Strahm, B. [2 ]
Lachenal, D. [2 ]
Guerin, C. [2 ]
Holman, Z. C. [1 ]
Zicarelli, F. [1 ]
Demaurex, B. [1 ]
Seif, J. [1 ]
Holovsky, J. [3 ]
Ballif, C. [1 ]
机构
[1] Ecole Polytech Fed Lausanne EPFL, Inst Microengn IMT, Photovolta & Thin Film Elect Lab, CH-2000 Neuchatel, Switzerland
[2] Roth & Rau Switzerland SA, CH-2000 Neuchatel, Switzerland
[3] Acad Sci Czech Republic, Inst Phys, Prague 16253 6, Czech Republic
关键词
AMORPHOUS-SILICON; SOLAR-CELLS; SPECTROSCOPIC ELLIPSOMETRY;
D O I
10.1063/1.3641899
中图分类号
O59 [应用物理学];
学科分类号
摘要
Silicon heterojunction solar cells have high open-circuit voltages thanks to excellent passivation of the wafer surfaces by thin intrinsic amorphous silicon (a-Si:H) layers deposited by plasma-enhanced chemical vapor deposition. We show a dramatic improvement in passivation when H-2 plasma treatments are used during film deposition. Although the bulk of the a-Si:H layers is slightly more disordered after H-2 treatment, the hydrogenation of the wafer/film interface is nevertheless improved with as-deposited layers. Employing H-2 treatments, 4 cm(2) heterojunction solar cells were produced with industry-compatible processes, yielding open-circuit voltages up to 725 mV and aperture area efficiencies up to 21%. (C) 2011 American Institute of Physics. [doi:10.1063/1.3641899]
引用
收藏
页数:3
相关论文
共 23 条
[1]   BOND SELECTIVITY IN SILICON FILM GROWTH [J].
BOLAND, JJ ;
PARSONS, GN .
SCIENCE, 1992, 256 (5061) :1304-1306
[2]  
CABARROCAS PRI, 2000, J NONCRYST SOLIDS, V31, P266
[3]   Abruptness of a-Si:H/c-Si interface revealed by carrier lifetime measurements [J].
De Wolf, Stefaan ;
Kondo, Michio .
APPLIED PHYSICS LETTERS, 2007, 90 (04)
[4]   Very fast light-induced degradation of a-Si:H/c-Si(100) interfaces [J].
De Wolf, Stefaan ;
Demaurex, Benedicte ;
Descoeudres, Antoine ;
Ballif, Christophe .
PHYSICAL REVIEW B, 2011, 83 (23)
[5]   Stretched-exponential a-Si:H/c-Si interface recombination decay [J].
De Wolf, Stefaan ;
Olibet, Sara ;
Ballif, Christophe .
APPLIED PHYSICS LETTERS, 2008, 93 (03)
[6]   The silane depletion fraction as an indicator for the amorphous/crystalline silicon interface passivation quality [J].
Descoeudres, A. ;
Barraud, L. ;
Bartlome, R. ;
Choong, G. ;
De Wolf, Stefaan ;
Zicarelli, F. ;
Ballif, C. .
APPLIED PHYSICS LETTERS, 2010, 97 (18)
[7]   Real-time monitoring and process control in amorphous/crystalline silicon heterojunction solar cells by spectroscopic ellipsometry and infrared spectroscopy [J].
Fujiwara, H ;
Kondo, M .
APPLIED PHYSICS LETTERS, 2005, 86 (03) :1-3
[8]   IDEAL HYDROGEN TERMINATION OF THE SI-(111) SURFACE [J].
HIGASHI, GS ;
CHABAL, YJ ;
TRUCKS, GW ;
RAGHAVACHARI, K .
APPLIED PHYSICS LETTERS, 1990, 56 (07) :656-658
[9]   Parameterization of the optical functions of amorphous materials in the interband region [J].
Jellison, GE ;
Modine, FA .
APPLIED PHYSICS LETTERS, 1996, 69 (03) :371-373
[10]   DEFECTS IN PLASMA-DEPOSITED A-SI-H [J].
KNIGHTS, JC ;
LUCOVSKY, G ;
NEMANICH, RJ .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1979, 32 (1-3) :393-403