Organic Field-Effect Transistors based on Highly Ordered Single Polymer Fibers

被引:218
作者
Wang, Suhao [1 ]
Kappl, Michael [1 ]
Liebewirth, Ingo [1 ]
Mueller, Maren [1 ]
Kirchhoff, Katrin [1 ]
Pisula, Wojciech [1 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
conjugated donor-acceptor copolymer; single polymer fibers; organic electronics; field-effect transistors; self-assembly; THIN-FILM TRANSISTORS; HIGH-PERFORMANCE; SEMICONDUCTING POLYMERS; CHARGE-TRANSPORT; COPOLYMERS; RIBBONS; SURFACE;
D O I
10.1002/adma.201103057
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrahigh-mobility organic field-effect transistors (OFETs) based on a CDT-BTZ donor-acceptor copolymer are realized by reaching high molecular order and pronounced alignment in single fibers within a short OFET channel via solution processing. The macromolecules directionally self-assemble in a quasi crystal-like order in the fibers providing in this way an unhindered charge carrier pathway with mobilities as high as 5.5 cm(2) V-1 s(-1).
引用
收藏
页码:417 / +
页数:5
相关论文
共 40 条
[31]  
Xiao K., 2007, ANGEW CHEM INT EDIT, V46, P2549
[32]   Single Crystals of Polythiophene with Different Molecular Conformations Obtained by Tetrahydrofuran Vapor Annealing and Controlling Solvent Evaporation [J].
Xiao, Xinli ;
Wang, Zongbao ;
Hu, Zhijun ;
He, Tianbai .
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (22) :7452-7460
[33]   Study on the Single Crystals of Poly(3-octylthiophene) Induced by Solvent-Vapor Annealing [J].
Xiao, Xinli ;
Hu, Zhijun ;
Wang, Zongbao ;
He, Tianbai .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (44) :14604-14610
[34]   Patterning of Conjugated Polymers for Organic Optoelectronic Devices [J].
Xu, Youyong ;
Zhang, Fan ;
Feng, Xinliang .
SMALL, 2011, 7 (10) :1338-1360
[35]   A high-mobility electron-transporting polymer for printed transistors [J].
Yan, He ;
Chen, Zhihua ;
Zheng, Yan ;
Newman, Christopher ;
Quinn, Jordan R. ;
Dotz, Florian ;
Kastler, Marcel ;
Facchetti, Antonio .
NATURE, 2009, 457 (7230) :679-U1
[36]   Synthesis and Processing of Monodisperse Oligo(fluorene-co-bithiophene)s into Oriented Films by Thermal and Solvent Annealing [J].
Zeng, Lichang ;
Yan, Feng ;
Wei, Simon K. -H. ;
Culligan, Sean W. ;
Chen, Shaw H. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (12) :1978-1986
[37]   Field-effect transistors based on a benzothiadiazole-cyclopentadithiophene copolymer [J].
Zhang, Ming ;
Tsao, Hoi Nok ;
Pisula, Wojciech ;
Yang, Changduk ;
Mishra, Ashok K. ;
Muellen, Klaus .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3472-+
[38]   Indacenodithiophene Semiconducting Polymers for High-Performance, Air-Stable Transistors [J].
Zhang, Weimin ;
Smith, Jeremy ;
Watkins, Scott E. ;
Gysel, Roman ;
McGehee, Michael ;
Salleo, Alberto ;
Kirkpatrick, James ;
Ashraf, Shahid ;
Anthopoulos, Thomas ;
Heeney, Martin ;
McCulloch, Iain .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (33) :11437-11439
[39]   Highly Sensitive, Air-Stable Photodetectors Based on Single Organic Sub-micrometer Ribbons Self-Assembled through Solution Processing [J].
Zhou, Yan ;
Wang, Lei ;
Wang, Jian ;
Pei, Jian ;
Cao, Yong .
ADVANCED MATERIALS, 2008, 20 (19) :3745-+
[40]   High-Performance Organic Field-Effect Transistors from Organic Single-Crystal Microribbons Formed by a Solution Process [J].
Zhou, Yan ;
Lei, Ting ;
Wang, Lei ;
Pei, Jian ;
Cao, Yong ;
Wang, Jian .
ADVANCED MATERIALS, 2010, 22 (13) :1484-+