Transition-metal- and organic-solvent-free: a highly efficient anaerobic process for selective oxidation of alcohols to aldehydes and ketones in water

被引：67

作者：

Gogoi, P ^{[1
]}

Konwar, D ^{[1
]}

机构：

[1] Reg Res Lab, Div Organ Chem, Jorhat 785006, Assam, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 19期

关键词：

D O I：

10.1039/b509527a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new system, I-2-KI-K2CO3-H2O, selectively oxidized alcohols to aldehydes and ketones under anaerobic condition in water at 90 degrees C with excellent yields. The process is green, mild and inexpensive.

引用

页码：3473 / 3475

页数：3

共 32 条

[1] Synthetic applications of nonmetal catalysts for homogeneous oxidations [J].

Adam, W ;

Saha-Möller, CR ;

Ganeshpure, PA .

CHEMICAL REVIEWS, 2001, 101 (11) :3499-3548

[2]

ANELLI PL, 1987, J ORG CHEM, V52, P2559

[3]

[Anonymous], COMPREHENSIVE ORGANI

[4] New reactions in water:: metal-free conversion of alcohols and ketones into α-iodoketones [J].

Barluenga, J ;

Marco-Arias, M ;

González-Bobes, F ;

Ballesteros, A ;

González, JM .

CHEMICAL COMMUNICATIONS, 2004, (22) :2616-2617

[5]

BEHNKE CJP, 1985, ALDRICH LIB 13C NMR

[6] Catalytic synthesis of aldehydes and ketones under mild conditions using TEMPO/Oxone [J].

Bolm, C ;

Magnus, AS ;

Hildebrand, JP .

ORGANIC LETTERS, 2000, 2 (08) :1173-1175

[7] Competing reactions of secondary alcohols with sodium hypochlorite promoted by phase-transfer catalysis [J].

Bright, ZR ;

Luyeye, CR ;

Morton, ASM ;

Sedenko, M ;

Landolt, RG ;

Bronzi, MJ ;

Bohovic, KM ;

Gonser, MWA ;

Lapainis, TE ;

Hendrickson, WH .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (02) :684-687

[8] Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes [J].

Gamez, P ;

Arends, IWCE ;

Reedijk, J ;

Sheldon, RA .

CHEMICAL COMMUNICATIONS, 2003, (19) :2414-2415

[9] Surfactant/I2/Water:: An efficient system for deprotection of oximes and imines to carbonyls under neutral conditions in water [J].

Gogoi, P ;

Hazarika, P ;

Konwar, D .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (05) :1934-1936

[10] DMSO/N2H4•H2O/I2/H2O/CH3CN:: A new system for selective oxidation of alcohols in hydrated media [J].

Gogoi, P ;

Sarmah, GK ;

Konwar, D .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (15) :5153-5154

← 1 2 3 4 →