Photocatalytic selective aerobic oxidation of alcohols to aldehydes and ketones by HPW/MCM-41 in ionic liquids

被引：25

作者：

Shen, Hao-Yu

Mao, Hong-Lei

Ying, Li-Yan

Xia, Qing-Hua

机构：

[1] Zhejiang Univ, Biol & Chem Engn Sch, Ningbo Inst Technol, Ningbo 315100, Zhejiang, Peoples R China

[2] Zhejiang Univ, Ningbo Inst Technol, Anal & Testing Ctr, Ningbo 315100, Zhejiang, Peoples R China

[3] Hubei Univ, Sch Chem & Mat Sci, Lab Adv Mat & New Catalysis, Wuhan 430062, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 276卷 / 1-2期

关键词：

selective oxidation of alcohols; ionic liquids; HPW/MCM-41; photocatalyst; solvent effect;

D O I：

10.1016/j.molcata.2007.05.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using HPW/MCM-41 as a heterogeneous photocatalyst in ionic liquids, [bmim]PF6, [omim]BF4 and [hmim]BF4. Comparative studies on the catalytic properties of HPWIMCM-41, HPW to MCM-41 were carried out. Some important variables, e.g. the loading amount of HPW on MCM-41 and the effects of different ionic liquids were discussed in this work. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：73 / 79

页数：7

共 66 条

[21] Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes [J].

Gilhespy, M ;

Lok, M ;

Baucherel, X .

CHEMICAL COMMUNICATIONS, 2005, (08) :1085-1086

[22] Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids [J].

Hemeon, I ;

Barnett, NW ;

Gathergood, N ;

Scammells, PJ ;

Singer, RD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2004, 57 (02) :125-128

[23] Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids [J].

Herrmann, WA ;

Böhm, VPW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (01) :141-145

[24] Comparison of the photoredox properties of polyoxometallates and semiconducting particles [J].

Hiskia, A ;

Mylonas, A ;

Papaconstantinou, E .

CHEMICAL SOCIETY REVIEWS, 2001, 30 (01) :62-69

[25] Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction [J].

Huddleston, JG ;

Willauer, HD ;

Swatloski, RP ;

Visser, AE ;

Rogers, RD .

CHEMICAL COMMUNICATIONS, 1998, (16) :1765-1766

[26] Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6 [J].

Jiang, N ;

Ragauskas, AJ .

ORGANIC LETTERS, 2005, 7 (17) :3689-3692

[27] Cu(II)-catalyzed selective aerobic oxidation of alcohols under mild conditions [J].

Jiang, Nan ;

Ragauskas, Arthur J. .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (18) :7087-7090

[28] A facile and efficient nucleophilic displacement reaction at room temperature in ionic liquids [J].

Judeh, ZMA ;

Shen, HY ;

Chi, BC ;

Feng, LC ;

Selvasothi, S .

TETRAHEDRON LETTERS, 2002, 43 (51) :9381-9384

[29] The first Bischler-Napieralski cyclization in a room temperature ionic liquid [J].

Judeh, ZMA ;

Ching, CB ;

Bu, J ;

McCluskey, A .

TETRAHEDRON LETTERS, 2002, 43 (29) :5089-5091

[30] NEW ACID CATALYST COMPRISING HETEROPOLY ACID ON A MESOPOROUS MOLECULAR-SIEVE MCM-41 [J].

KOZHEVNIKOV, IV ;

SINNEMA, A ;

JANSEN, RJJ ;

PAMIN, K ;

VANBEKKUM, H .

CATALYSIS LETTERS, 1995, 30 (1-4) :241-252

← 1 2 3 4 5 6 7 →