Polyelectrolyte Wrapping Layers Control Rates of Photothermal Molecular Release from Gold Nanorods

被引:55
作者
Huang, Jingyu [1 ]
Jackson, Kaliah S. [1 ]
Murphy, Catherine J. [1 ]
机构
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
关键词
Gold nanorod; continuous-wave laser; photothermal; polyelectrolyte coating; drug delivery; METAL NANOPARTICLES; TRIGGERED RELEASE; REMOTE RELEASE; DRUG-DELIVERY; AU NANORODS; NANOCAGES; THERAPY; SURFACE; CELLS; DNA;
D O I
10.1021/nl3007402
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold nanorods show great promise as light-controlled molecular release systems. Dye molecules were loaded within a variable number of polyelectrolyte multilayers wrapped around gold nanorods. The dye photoinduced release rate depended on the quantity and type of polyelectrolyte trapping layers and could be tuned by a factor of 100. Only two molecular capping layers were sufficient to turn off release. Comparison of the phototriggered molecular release rate to a pure thermal experiment provides an estimate of the effective temperature of the nanorod solution upon irradiation.
引用
收藏
页码:2982 / 2987
页数:6
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