Reliably Counting Atomic Planes of Few-Layer Graphene (n > 4)

被引:128
作者
Koh, Yee Kan [1 ,2 ,4 ]
Bae, Myung-Ho [3 ]
Cahill, David G. [1 ,2 ]
Pop, Eric [3 ]
机构
[1] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA
[2] Univ Illinois, Frederick Seitz Mat Res Lab, Urbana, IL 61801 USA
[3] Univ Illinois, Dept Elect & Comp Engn, Micro & Nanotechnol Lab, Urbana, IL 61801 USA
[4] Natl Univ Singapore, Dept Mech Engn, Singapore 117548, Singapore
关键词
few-layer graphene; number of graphene layers; Raman spectroscopy; graphene thickness; absorbance of monolayer graphene; field-effect mobility of carriers; electrostatic interlayer screening; RAMAN-SPECTROSCOPY; SCATTERING; FILMS; SIO2;
D O I
10.1021/nn102658a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate a reliable technique for counting atomic planes (n) of few-layer graphene (FLG) on SiO2/Si substrates by Raman spectroscopy. Our approach is based on measuring the ratio of the integrated intensity of the G graphene peak and the optical phonon peak of Si, I(G)/I(Si); and is particularly us:dill in the, range n > 4 where few methods exist. We compare out results with atomic force microscopy (AFM) measurements and Fresnel equation calculations. Then, we apply out method to unambiguously identify n of FLG devices on SiO2 and find that the mobility (mu approximate to 2000 cm(2) V-1 s(-1)) is independent of layer thickness for n > 4. Our findings suggest that electrical transport in gated FLG devices is dominated by carriers near the FLG/SiO2 interface and is thus limited by the environment even for n > 4.
引用
收藏
页码:269 / 274
页数:6
相关论文
共 34 条
[1]   Making graphene visible [J].
Blake, P. ;
Hill, E. W. ;
Castro Neto, A. H. ;
Novoselov, K. S. ;
Jiang, D. ;
Yang, R. ;
Booth, T. J. ;
Geim, A. K. .
APPLIED PHYSICS LETTERS, 2007, 91 (06)
[2]   Rayleigh imaging of graphene and graphene layers [J].
Casiraghi, C. ;
Hartschuh, A. ;
Lidorikis, E. ;
Qian, H. ;
Harutyunyan, H. ;
Gokus, T. ;
Novoselov, K. S. ;
Ferrari, A. C. .
NANO LETTERS, 2007, 7 (09) :2711-2717
[3]   Biased bilayer graphene: Semiconductor with a gap tunable by the electric field effect [J].
Castro, Eduardo V. ;
Novoselov, K. S. ;
Morozov, S. V. ;
Peres, N. M. R. ;
Dos Santos, J. M. B. Lopes ;
Nilsson, Johan ;
Guinea, F. ;
Geim, A. K. ;
Castro Neto, A. H. .
PHYSICAL REVIEW LETTERS, 2007, 99 (21)
[4]   Intrinsic and extrinsic performance limits of graphene devices on SiO2 [J].
Chen, Jian-Hao ;
Jang, Chaun ;
Xiao, Shudong ;
Ishigami, Masa ;
Fuhrer, Michael S. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :206-209
[5]  
Craciun MF, 2009, NAT NANOTECHNOL, V4, P383, DOI [10.1038/NNANO.2009.89, 10.1038/nnano.2009.89]
[6]   Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor [J].
Das, A. ;
Pisana, S. ;
Chakraborty, B. ;
Piscanec, S. ;
Saha, S. K. ;
Waghmare, U. V. ;
Novoselov, K. S. ;
Krishnamurthy, H. R. ;
Geim, A. K. ;
Ferrari, A. C. ;
Sood, A. K. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :210-215
[7]   Mobility and saturation velocity in graphene on SiO2 [J].
Dorgan, Vincent E. ;
Bae, Myung-Ho ;
Pop, Eric .
APPLIED PHYSICS LETTERS, 2010, 97 (08)
[8]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[9]   Ab initio study of gap opening and screening effects in gated bilayer graphene [J].
Gava, Paola ;
Lazzeri, Michele ;
Saitta, A. Marco ;
Mauri, Francesco .
PHYSICAL REVIEW B, 2009, 79 (16)
[10]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534