Conjugated Copolymers of Vinylene Flanked Naphthalene Diimide

被引：52

作者：

Fei, Zhuping ^{[1
,2
]}

Han, Yang ^{[1
,2
,3
]}

Martin, Jaime ^{[2
,4
]}

Scholes, Fiona H. ^{[5
]}

Al-Hashimi, Mohammed ^{[7
]}

AlQaradawi, Siham Y. ^{[6
]}

Stingelin, Natalie ^{[2
,4
]}

Anthopoulos, Thomas D. ^{[2
,3
]}

Heeney, Martin ^{[1
,2
]}

机构：

[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England

[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England

[3] Imperial Coll London, Dept Phys, London SW7 2AZ, England

[4] Imperial Coll London, Dept Mat, London SW7 2AZ, England

[5] CSIRO Mfg, Private Bag 10, Clayton, Vic 3169, Australia

[6] Qatar Univ, Dept Chem & Earth Sci, POB 2713, Doha, Qatar

[7] Texas A&M Univ Qatar, Dept Chem, POB 23874, Doha, Qatar

来源：

MACROMOLECULES | 2016年 / 49卷 / 17期

关键词：

FIELD-EFFECT TRANSISTORS; CHANNEL ORGANIC TRANSISTORS; HIGH-ELECTRON-MOBILITY; POLYMER SOLAR-CELLS; N-CHANNEL; CHARGE-TRANSPORT; SEMICONDUCTING POLYMERS; HIGH-PERFORMANCE; DIRECT ARYLATION; HIGH HOLE;

D O I：

10.1021/acs.macromol.6b01423

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the synthesis of a novel naphthalene diimide (NDI) monomer containing two (tributylstannyl)vinyl groups. The utility of this building block is demonstrated by its copolymerization with five different electron-rich comonomers under Stille conditions. The resulting high molecular weight polymers show red-shifted optical absorptions in comparison to the analogous polymers without the vinylene spacer and a significant increase in the intensity of the low-energy intramolecular charge transfer band. The polymers all exhibit ambipolar behavior in bottom-gate, top-contact organic thin-film transistors. The insertion of a solution-processed barium hydroxide layer between the polymer and the gold electrode led to unipolar behavior with improved electron mobilities.

引用

页码：6384 / 6393

页数：10

共 52 条

[1] n-Type Organic Semiconductors in Organic Electronics [J].

Anthony, John E. ;

Facchetti, Antonio ;

Heeney, Martin ;

Marder, Seth R. ;

Zhan, Xiaowei .

ADVANCED MATERIALS, 2010, 22 (34) :3876-3892

[2] Ambipolar organic field-effect transistors based on a solution-processed methanofullerene [J].

Anthopoulos, TD ;

Tanase, C ;

Setayesh, S ;

Meijer, EJ ;

Hummelen, JC ;

Blom, PWM ;

de Leeuw, DM .

ADVANCED MATERIALS, 2004, 16 (23-24) :2174-+

[3] Air-stable ambipolar organic transistors [J].

Anthopoulos, Thomas D. ;

Anyfantis, G. C. ;

Papavassiliou, G. C. ;

de Leeuw, Dago M. .

APPLIED PHYSICS LETTERS, 2007, 90 (12)

[4] Air-stable complementary-like circuits based on organic ambipolar transistors [J].

Anthopoulos, Thomas D. ;

Setayesh, Sepas ;

Smits, Edsger ;

Colle, Michael ;

Cantatore, Eugenio ;

de Boer, Bert ;

Blom, Paul W. M. ;

de Leeuw, Dago M. .

ADVANCED MATERIALS, 2006, 18 (14) :1900-+

[5] Materials and Applications for Large Area Electronics: Solution-Based Approaches [J].

Arias, Ana Claudia ;

MacKenzie, J. Devin ;

McCulloch, Iain ;

Rivnay, Jonathan ;

Salleo, Alberto .

CHEMICAL REVIEWS, 2010, 110 (01) :3-24

[6] High electron mobility in ladder polymer field-effect transistors [J].

Babel, A ;

Jenekhe, SA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (45) :13656-13657

[7] Naphthalenediimide-Based Copolymers Incorporating Vinyl-Linkages for High-Performance Ambipolar Field-Effect Transistors and Complementary-Like Inverters under Air [J].

Chen, Huajie ;

Guo, Yunlong ;

Mao, Zupan ;

Yu, Gui ;

Huang, Jianyao ;

Zhao, Yan ;

Liu, Yunqi .

CHEMISTRY OF MATERIALS, 2013, 25 (18) :3589-3596

[8] Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors [J].

Chen, Zhihua ;

Zheng, Yan ;

Yan, He ;

Facchetti, Antonio .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :8-+

[9] High-Performance Ambipolar Diketopyrrolopyrrole-Thieno[3,2-b]thiophene Copolymer Field-Effect Transistors with Balanced Hole and Electron Mobilities [J].

Chen, Zhuoying ;

Lee, Mi Jung ;

Ashraf, Raja Shahid ;

Gu, Yun ;

Albert-Seifried, Sebastian ;

Nielsen, Martin Meedom ;

Schroeder, Bob ;

Anthopoulos, Thomas D. ;

Heeney, Martin ;

McCulloch, Iain ;

Sirringhaus, Henning .

ADVANCED MATERIALS, 2012, 24 (05) :647-+

[10] Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications [J].

Durban, Matthew M. ;

Kazarinoff, Peter D. ;

Luscombe, Christine K. .

MACROMOLECULES, 2010, 43 (15) :6348-6352

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