Epitaxial growth of ZnO thin films exhibiting room-temperature ultraviolet emission by atmospheric pressure chemical vapor deposition

被引:19
作者
Kaiya, K
Omichi, K
Takahashi, N
Nakamura, T
Okamoto, S
Yamamoto, H
机构
[1] Shizuoka Univ, Grad Sch Sci & Engn, Hamamatsu, Shizuoka 4328561, Japan
[2] Shizuoka Univ, Fac Engn, Dept Mat Sci & Technol, Hamamatsu, Shizuoka 4328561, Japan
[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan
[4] Tokyo Univ Technol, Dept Engn, Hachioji, Tokyo 1928580, Japan
关键词
ZnO; ZnI2; atmospheric pressure halide vapor phase epitaxy; exciton emission;
D O I
10.1016/S0040-6090(02)00113-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZnO films have been grown on sapphire(0001) substrates by means of the atmospheric pressure halide vapor phase epitaxy technique using ZnI2, and O-2 as starting materials. The ZnO films showed a full width at half maximum of the (0002) X-ray peak of 20.2 min and a reflection high-energy electron diffraction pattern similar to that of a single crystal. A band-edge emission at 381.0 nm was observed in the photoluminescence spectra at room temperature. In addition, the crystal quality and optical property of ZnO films are also discussed in comparison with that in the ZnCl2 system. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:116 / 119
页数:4
相关论文
共 13 条
[1]   Growth of ZnO single crystal thin films on c-plane (0 0 0 1) sapphire by plasma enhanced molecular beam epitaxy [J].
Chen, YF ;
Bagnall, DM ;
Zhu, ZQ ;
Sekiuchi, T ;
Park, KT ;
Hiraga, K ;
Yao, T ;
Koyama, S ;
Shen, MY ;
Goto, T .
JOURNAL OF CRYSTAL GROWTH, 1997, 181 (1-2) :165-169
[2]   GALLIUM NITRIDE FILMS [J].
CHU, TL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (07) :1200-&
[3]  
FERGUSSON RR, 1964, J ELECTROCHEM SOC, V111, P583
[4]  
JURGENSEN H, 1981, P 8 INT S GAAS REL C, P55
[5]   Growth of a high quality ZnO film on sapphire by atmospheric pressure halide vapor phase epitaxy using ZnO buffer layers [J].
Kaiya, K ;
Omichi, K ;
Takahashi, N ;
Nakamura, T ;
Okamoto, S ;
Yamamoto, H .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (04) :969-972
[6]   VAPOR-PHASE EPITAXIAL-GROWTH OF GAN ON GAAS, GAP, SI, AND SAPPHIRE SUBSTRATES FROM GABR3 AND NH3 [J].
MORIMOTO, Y ;
UCHIHO, K ;
USHIO, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1973, 120 (12) :1783-1785
[7]   Growth of ZnO thin films exhibiting room-temperature ultraviolet emission by means of atmospheric pressure vapor-phase epitaxy [J].
Omichi, K ;
Kaiya, K ;
Takahashi, N ;
Nakamura, T ;
Okamoto, S ;
Yamamoto, H .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (02) :262-263
[8]   AP-HVPE growth of ZnO with room-temperature ultraviolet emission [J].
Omichi, K ;
Takahashi, N ;
Nakamura, T ;
Yoshioka, M ;
Okamoto, S ;
Yamamoto, H .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :3158-3160
[9]  
Reynolds D. C., 1970, Proceedings of the 10th international conference on the physics of semiconductors, P519
[10]   Similarities in the bandedge and deep-centre photoluminescence mechanisms of ZnO and GaN [J].
Reynolds, DC ;
Look, DC ;
Jogai, B ;
Morkoc, H .
SOLID STATE COMMUNICATIONS, 1997, 101 (09) :643-646