At temperatures between 500 degree and 950 degree C, in an oxygen ambient, a flux of either negative or positive oxygen ions, generated via a point-to-plane corona discharge, is directed to the front side of a silicon wafer. Electrical contact to the wafer was made via the back side. Both ion beam polarities lead to oxidation enhancement, but with very different oxide thickness profiles, even though the ion beam current density profiles in the gas phase at the surface are almost identical. Wafer orientation, P//O//2, current, temperature, and time dependences have been studied.