Interstitial copper-related center in n-type silicon

n-type silicon samples were measured by deep level transient spectroscopy (DLTS) immediately (within one hour of storage at room temperature, required for the preparation of Schottky-diodes) after copper diffusion and quench. A donor level at E-c-(0.15+/-0.01) eV with a concentration of up to 10(13) cm(-3) was detected. The amplitude of the DLTS peak decreased with the time of storage at room temperature, and stabilized at a concentration (4 to 7)x10(11) cm(-3) after 15-20 h. The activation energies and prefactors of the decay of the DLTS peak in n-type Si and the reactivation of copper-compensated boron in p-type Si concur. This correlation suggests that the deep level is interstitial copper itself or a complex of interstitial copper. (C) 1997 American Institute of Physics.