Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties

被引：49

作者：

Centrone, Andrea ^{[1
]}

Harada, Takuya ^{[1
]}

Speakman, Scott ^{[2
]}

Hatton, T. Alan ^{[1
]}

机构：

[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA

[2] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA

来源：

SMALL | 2010年 / 6卷 / 15期

基金：

美国国家科学基金会;

关键词：

magnetic properties; metal-organic frameworks; micro-wave synthesis; SQUID; XPS; HIGH-CAPACITY; SELECTIVE ADSORPTION; MICROWAVE SYNTHESIS; CARBON-DIOXIDE; STORAGE; HYDROGEN; METHANE; MIL-47; SEPARATION; CHEMISTRY;

D O I：

10.1002/smll.201000773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The facile microwave syntheses of MIL-47 and six new vanadium-metal- organic-framework (V-MOF) materials are described. Small changes in the material crystal structure or removal of guest molecules affects the interactions between the V ions and, consequently, the magnetic properties of the MOF (see image). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA Weinheim.

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页码：1598 / 1602

页数：5

相关论文

共 36 条

[1] Activation of the metal-organic framework MIL-47 for selective adsorption of xylenes and other difunctionalized aromatics [J].

Alaerts, Luc ;

Maes, Michael ;

Jacobs, Pierre A. ;

Denayer, Joeri F. M. ;

De Vos, Dirk E. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (20) :2979-2985

[2] Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47 [J].

Alaerts, Luc ;

Kirschhock, Christine E. A. ;

Maes, Michael ;

van der Veen, Monique A. ;

Finsy, Vincent ;

Depla, Anouschka ;

Martens, Johan A. ;

Baron, Gino V. ;

Jacobs, Pierre A. ;

Denayer, Joeri E. M. ;

De Vos, Dirk E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4293-4297

[3] XPS study of vanadium surface oxidation by oxygen ion bombardment [J].

Alov, N ;

Kutsko, D ;

Spirovová, I ;

Bastl, Z .

SURFACE SCIENCE, 2006, 600 (08) :1628-1631

[4] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mirkin, Chad A. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

CHEMICAL COMMUNICATIONS, 2008, (35) :4135-4137

[5]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[6]

2-Y

[7] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].

Bourrelly, S ;

Llewellyn, PL ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521

[8] Metal-organic frameworks with high capacity and selectivity for harmful gases [J].

Britt, David ;

Tranchemontagne, David ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (33) :11623-11627

[9] Raman spectra of hydrogen and deuterium adsorbed on a metal-organic framework [J].

Centrone, A ;

Siberio-Pérez, DY ;

Millward, AR ;

Yaghi, OM ;

Matzger, AJ ;

Zerbi, G .

CHEMICAL PHYSICS LETTERS, 2005, 411 (4-6) :516-519

[10] New methodological approach for the vanadium K-edge X-ray absorption near-edge structure interpretation: Application to the speciation of vanadium in oxide phases from steel slag [J].

Chaurand, Perrine ;

Rose, Jerome ;

Briois, Valerie ;

Salome, Murielle ;

Proux, Olivier ;

Nassif, Vivian ;

Olivi, Luca ;

Susini, Jean ;

Hazemann, Jean-Louis ;

Bottero, Jean-Yves .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (19) :5101-5110

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