Electronic control of the Bergman cycloaromatization: Synthesis and chemistry of chloroenediynes

被引：41

作者：

Jones, GB ^{[1
]}

Plourde, GW ^{[1
]}

机构：

[1] Northeastern Univ, Dept Chem, Bioorgan & Med Chem Labs, Boston, MA 02115 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 12期

关键词：

D O I：

10.1021/ol0059394

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A series of cyclic mono- and dichloroenediynes have been prepared using an intramolecular carbenoid coupling reaction. The halogen atom had a retardative effect on Bergman cycloaromatization in every case examined, and atom transfer chemistry was demonstrated, resulting in formation of adducts.

引用

页码：1757 / 1759

页数：3

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