Changes in profiles of implanted impurities in siliconand associated microstructural changes as a result of high-power laser pulses have been studied using ion- scattering channeling and transmission electron microscopy. The results show a significant segregation in the form of precipitates at and away from the dislocations in the near-surface regions for impurities such as copper and iron in silicon which have very low equilibrium solubilities and equilibrium distribution coefficients.