Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

被引：223

作者：

Junge, Kathrin ^{[1
]}

Wendt, Bianca ^{[1
]}

Shaikh, Nadim ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期

关键词：

BIOMIMETIC TRANSFER HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; ENANTIOSELECTIVE CATALYSIS; PORPHYRIN CATALYSTS; NITRO-COMPOUNDS; KETONES; HYDROSILYLATION; COMPLEXES; CONVENIENT; ALDEHYDES;

D O I：

10.1039/b924228g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The iron-catalyzed reduction of aromatic nitro compounds to the corresponding anilines applying organosilanes is reported. In the presence of FeX2-R3P catalysts a series of nitroarenes is selectively reduced tolerating a wide range of functional groups.

引用

页码：1769 / 1771

页数：3

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